msn.com would have great value - but chances of it selling? unlikely. I would say google.com would be the most expensive domain name to get.
Anyway from wikipedia:
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According to Guinness World Records and MSNBC, the most expensive domain name sales on record as of 2004 were: Business.com for $7.5 million in December 1999, AsSeenOnTv.com for $5.1 million in January 2000, Altavista.com for $3.3 million in August 1998, Wine.com for $2.9 million in September 1999, CreditCards.com for $2.75 million in July 2004, and Autos.com for $2.2 million in December 1999.
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