Each domain will have its own smtp address. If your friend has got a domain name abcadabca.com then his SMTP address is abcadabca.com or mail.abcadabca.com
Make sure that you configure his DNS properly or else the SMTP wotn work with the domain name. You can use IP of your
VPS Hosting for pop3 but for smtp you will need a configured domain name residing on your
VPS Hosting.
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